Natural abundance

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Relative abundance of elements.png

In chemistry, natural abundance (NA) refers to the abundanceclarification needed of isotopes of a chemical element as naturally found on a planet. The relative atomic mass (a weighted average) of these isotopes is the atomic weight listed for the element in the periodic table. The abundance of an isotope varies from planet to planet, and even from place to place on the Earth, but remains relatively constant in time.

As an example, uranium has three naturally occurring isotopes: 238U, 235U and 234U. Their respective NA range from 99.2739 - 99.2752%, 0.7198 - 0.7202%, and 0.0050 - 0.0059%.1 For example, if 100,000 uranium atoms were analyzed, one would expect to find approximately 99,275 238U atoms, 720 235U atoms, and no more than 5 or 6 234U atoms. This is because 238U is much more stable than 235U or 234U, as the half-life of each isotope reveals: 4.468×109 years for 238U compared to 7.038×108 years for 235U and 245,500 years for 234U.

Exactly because the different uranium isotopes have different half-lives, when the Earth was younger, the isotopic composition of uranium was different. As an example, 1.7 billion years ago the NA of 235U was 3.1% compared to today's 0.7%, and for that reason a natural nuclear fission reactor was able to form, something that cannot happen today.

However, the natural abundance of a given isotope is also affected by the probability of its creation in nucleosynthesis (as in the case of samarium; radioactive 147Sm and 148Sm are much more abundant than stable 144Sm) and by production of a given isotope by natural radioactive isotopes (as in the case of radiogenic isotopes of lead).

Deviations from natural abundance

It is now known from study of the sun and primitive meteorites that the solar system was initially almost homogeneous in isotopic composition. Deviations from the (evolving) galactic average, locally-sampled around the time that the sun's nuclear burning began, can generally be accounted for by mass fractionation (see the article on mass-independent fractionation) plus a limited number of nuclear decay and transmutation processes.2 There is also evidence for injection of short-lived (now extinct) isotopes from a nearby supernova explosion that may have triggered solar nebula collapse.3 Hence deviations from natural abundance on earth are often measured in parts per thousand (per mil or ‰‰) because they are less than one percent (%). The single exception to this lies with the presolar grains found in primitive meteorites. These bypassed the homogenization, and often carry the nuclear signature of specific nucleosynthesis processes in which their elements were made.4 In these materials, deviations from "natural abundance" are sometimes measured in factors of 100.

See also

Footnotes and References

  1. ^ Uranium Isotopes, retrieved 14 March 2012 
  2. ^ Robert N. Clayton (1978) Isotopic anomalies in the early solar system, Annual Review of Nuclear and Particle Science 28:501-522.
  3. ^ Ernst Zinner (2003) An isotopic view of the early solar system, Science 300:5617, 265-267.
  4. ^ Ernst Zinner (1998) Stellar nucleosynthesis and the isotopic composition of presolar grains from primitive meteorites, Annual Review of Earth and Planetary Sciences 26:147-188.

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